Spitzer Space Telescope - Guaranteed Time Observer Proposal #50116 Investigating the Dust Chemistry in Pre-Planetary Nebulae Principal Investigator: Giovanni Fazio Institution: Harvard-Smithsonian Astrophysical Observatory Technical Contact: Luciano Cerrigone, Harvard-Smithsonian Center for Astrophysics Co-Investigators: Luciano Cerrigone, CfA Joseph Hora, CfA Grazia Umana, INAF, Italy Corrado Trigilio, INAF, Italy Massimo Marengo, CfA Science Category: evolved stars/pn/sne Observing Modes: IracMap IrsStare Hours Approved: 10 Abstract: We propose to extend our study of young planetary nebulae/transition objects with IRAC and IRS to 1) confirm the result of the previous observations of a high (50%) incidence of dual-dust chemistry in these objects, and 2) examine a sample of objects at an earlier evolutionary state to determine the point at which the emission features arise in the shells around these objects. These data, along with ground-based high spatial resolution imaging, will provide information on the mechanisms that lead to their asymmetric shapes.