Spitzer Space Telescope - General Observer Proposal #80082 Observations of Carbon Dioxide in the Coma of Comet C/2009 P1 Garradd Principal Investigator: Adam McKay Institution: New Mexico State University Technical Contact: Adam McKay, New Mexico State University Co-Investigators: William Reach, NASA Ames Michael Kelley, University of Maryland Michael DiSanti, Goddard Space Flight Center Nancy Chanover, New Mexico State University Science Category: comets Observing Modes: IRAC Post-Cryo Mapping Hours Approved: 8.6 Abstract: The study of cometary composition is important to understanding the formation and evolution of our solar system. Comets have undergone very little thermal evolution in their lifetimes, which results in their near pristine composition. The nucleus of a comet is very rarely detected directly. Instead, we observe the coma that surrounds the nucleus. Physical and chemical processes in the coma affect its composition, and therefore coma composition is not a direct representation of nuclear composition. An important trend is the observed variation of coma composition with heliocentric distance, most likely influenced by the volatility of the main surface ices, H2O, CO2, and CO. Infrared studies of these molecules are complicated by telluric features, so often daughter molecules of these species such as OH are observed instead. A potentially effective tracer for these primary ices is atomic oxygen in the coma. However, the relationship between these ices and atomic oxygen is only understood at a qualitative level. We propose to use Spitzer observations in IRAC's 4.5 micron band pass to observe the CO2 v3 band at 4.26 microns in comet C/2009 P1 Garradd. These observations will be coordinated with observations of atomic oxygen obtained at Apache Point Observatory and observations of H2O at NASA's Infrared Telescope Facility (IRTF). These near simultaneous observations of H2O, CO2, and atomic oxygen in a cometary coma will increase our understanding of the link between these primary ices and atomic oxygen. With a complete understanding of the relationship between atomic oxygen and the primary ices on the nucleus, observations of atomic oxygen can serve as a powerful proxy for the production of these primary volatiles and aid our understanding of the variation in coma composition as a function of heliocentric distance, and therefore the composition of the nucleus and how our solar system was formed.